Role of Ni dopant on the improvement of ZnO-based reusable photocatalytic materials

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Published: Dec 28, 2024
DOI: https://doi.org/10.62755/greensusmater.2024.1.2.51-56
Keywords:
methylene blue, spray pyrolysis, reusable photocatalyst, ZnO:Ni film

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Eka Nurfani
Department of Materials Engineering, Faculty of Industrial Technology, Sumatera Institute of Technology (ITERA), Lampung 35365, Indonesia
Azka R. Firdaus
Department of Materials Engineering, Faculty of Industrial Technology, Sumatera Institute of Technology (ITERA), Lampung 35365, Indonesia
Dedi Triyadi
Department of Materials Engineering, Faculty of Industrial Technology, Sumatera Institute of Technology (ITERA), Lampung 35365, Indonesia
Aditya Rianjanu
Department of Materials Engineering, Faculty of Industrial Technology, Sumatera Institute of Technology (ITERA), Lampung 35365, Indonesia

Abstract

This study investigates the impact of Ni doping on the enhancement of ZnO-based reusable photocatalytic materials. Ni concentrations derived from nickel chloride hexahydrate were 0 wt% (ZN-1), 1 wt% (ZN-2), and 3 wt% (ZN-3). Field-emission scanning electron microscopy (FESEM) analysis reveals a significant morphological transformation from flower-like structures in pure ZnO to nanoridges in Ni-doped ZnO. X-ray diffraction data indicate a reduction in crystalline quality with Ni incorporation. UV-Vis spectroscopy shows an increase in the bandgap from 3.22 eV for pure ZnO (ZN-1) to 3.34 eV for Ni-doped ZnO (ZN-2 and ZN-3). Photocatalytic efficiency improves markedly, achieving 30%, 60%, and 80% degradation for ZN-1, ZN-2, and ZN-3, respectively, after 1-hour illumination. Notably, the photocatalytic performance remains robust even after five recycling cycles. These findings reveal the potential of Ni-doped ZnO as a cost-effective, reusable, and highly efficient photocatalytic material.

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How to Cite
Nurfani, E., Firdaus, A. R., Triyadi, D., & Rianjanu, A. (2024). Role of Ni dopant on the improvement of ZnO-based reusable photocatalytic materials. Greensusmater, 1(2), 51–56. https://doi.org/10.62755/greensusmater.2024.1.2.51-56
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Vol. 1 No. 2 (2024): December
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