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Hydrothermal synthesis of Nb2O5-natural zeolite composite for enhanced adsorptive removal of anionic and cationic dye

  • Yohana Anastasya
    Yohana Anastasya
    Department of Environmental Engineering, Faculty of Infrastructure and Regional Technology, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
  • Sephia Amanda Muhtar
    Sephia Amanda Muhtar
    Department of Environmental Engineering, Faculty of Infrastructure and Regional Technology, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
  • Andika Munandar
    Andika Munandar
    Department of Environmental Engineering, Faculty of Infrastructure and Regional Technology, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
  • Ayu Rahayu Saraswati
    Ayu Rahayu Saraswati
    Department of Agricultural Industrial Technology, Faculty of Industrial Technology, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
  • Tarmizi Taher
    Tarmizi Taher*
    Department of Environmental Engineering, Faculty of Infrastructure and Regional Technology, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
    * Corresponding author
Department of Environmental Engineering, Faculty of Infrastructure and Regional Technology, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
Department of Environmental Engineering, Faculty of Infrastructure and Regional Technology, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
Department of Environmental Engineering, Faculty of Infrastructure and Regional Technology, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
Department of Agricultural Industrial Technology, Faculty of Industrial Technology, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
Department of Environmental Engineering, Faculty of Infrastructure and Regional Technology, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
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Abstract

The imperative to mitigate dye pollution from wastewater has propelled the exploration of efficient adsorbents. This study deals with the preparation and evaluation of Nb2O5-supported natural zeolite (NbX_NZ) for enhanced dye adsorption performance. A facile hydrothermal method was employed to prepare NbX_NZ with varying niobium precursor loadings. Comprehensive material characterization employing FESEM, EDX, TGA, XRD, and FTIR analyses elucidate the successful incorporation of Nb2O5, revealing altered morphological and thermal properties. The adsorption test exhibited a notable augmentation in adsorption capacity for Congo red dye, particularly with the Nb15_NZ sample, showcasing a nearly two-fold increase compared to the parent natural zeolite. The findings underscore the potential of NbX_NZ as promising materials for anionic dye adsorption, paving the way for advancing wastewater treatment solutions and further investigations into metal oxide-modified zeolites.

References

  1. [1] E. Pérez-Botella, S. Valencia, F. Rey, Zeolites in Adsorption Processes: State of the Art and Future Prospects, Chem Rev 122 (2022) 17647–17695. https://doi.org/10.1021/acs.chemrev.2c00140.
  2. [2] Y. Li, J. Yu, Emerging applications of zeolites in catalysis, separation and host–guest assembly, Nat Rev Mater 6 (2021) 1156–1174. https://doi.org/10.1038/s41578-021-00347-3.
  3. [3] T. Taher, E.K.A. Melati, M. Febrina, S. Maulana, M.A. Asagabaldan, A. Rianjanu, A. Lesbani, R.R. Mukti, Effect of Desilication on Indonesian Natural Zeolite for the Enhancement of Ammonium Ion Removal from Aqueous Solutions, Silicon 16 (2024) 1309–1319. https://doi.org/10.1007/s12633-023-02758-z.
  4. [4] T. Shindhal, P. Rakholiya, S. Varjani, A. Pandey, H.H. Ngo, W. Guo, H.Y. Ng, M.J. Taherzadeh, A critical review on advances in the practices and perspectives for the treatment of dye industry wastewater, Bioengineered 12 (2021) 70–87. https://doi.org/10.1080/21655979.2020.1863034.
  5. [5] H.M. Solayman, Md.A. Hossen, A. Abd Aziz, N.Y. Yahya, K.H. Leong, L.C. Sim, M.U. Monir, K.-D. Zoh, Performance evaluation of dye wastewater treatment technologies: A review, J Environ Chem Eng 11 (2023) 109610. https://doi.org/10.1016/j.jece.2023.109610.
  6. [6] M.D. Khan, A. Singh, M.Z. Khan, S. Tabraiz, J. Sheikh, Current perspectives, recent advancements, and efficiencies of various dye-containing wastewater treatment technologies, Journal of Water Process Engineering 53 (2023) 103579. https://doi.org/10.1016/j.jwpe.2023.103579.
  7. [7] Y. Zhou, J. Lu, Y. Zhou, Y. Liu, Recent advances for dyes removal using novel adsorbents: A review, Environmental Pollution 252 (2019) 352–365. https://doi.org/10.1016/j.envpol.2019.05.072.
  8. [8] A. Rianjanu, T. Taher, F. Desriani, R.O. Delmita, A.G.N. Sianturi, S.A. Muhtar, B. Ariwahjoedi, N.I. Khamidy, D.R. Adhika, M.F. Arif, Examining the influence of sintering temperatures on the efficiency of 3D-printed natural zeolite for methylene blue dye adsorption, Results in Surfaces and Interfaces 17 (2024) 100337. https://doi.org/10.1016/j.rsurfi.2024.100337.
  9. [9] M. Popaliya, A. Mishra, Modified zeolite as an adsorbent for dyes, drugs, and heavy metal removal: a review, International Journal of Environmental Science and Technology 20 (2023) 12919–12936. https://doi.org/10.1007/s13762-022-04603-z.
  10. [10] C. Ferreira, A. Araujo, V. Calvino-Casilda, M.G. Cutrufello, E. Rombi, A.M. Fonseca, M.A. Bañares, I.C. Neves, Y zeolite-supported niobium pentoxide catalysts for the glycerol acetalization reaction, Microporous and Mesoporous Materials 271 (2018) 243–251. https://doi.org/10.1016/j.micromeso.2018.06.010.
  11. [11] N. Zhu, M. Zhang, G. Qiu, H. Tian, Y. Liu, One-pot synthesis of 5-hydroxymethylfurfural from cellobiose and sucrose using niobium-modified montmorillonite catalysts, Molecular Catalysis 532 (2022) 112720. https://doi.org/10.1016/j.mcat.2022.112720.
  12. [12] S. Liu, Y. Ding, P. Li, K. Diao, X. Tan, F. Lei, Y. Zhan, Q. Li, B. Huang, Z. Huang, Adsorption of the anionic dye Congo red from aqueous solution onto natural zeolites modified with N,N-dimethyl dehydroabietylamine oxide, Chemical Engineering Journal 248 (2014) 135–144. https://doi.org/10.1016/j.cej.2014.03.026.
  13. [13] E.P. Favvas, C.G. Tsanaktsidis, A.A. Sapalidis, G.T. Tzilantonis, S.K. Papageorgiou, A.Ch. Mitropoulos, Clinoptilolite, a natural zeolite material: Structural characterization and performance evaluation on its dehydration properties of hydrocarbon-based fuels, Microporous and Mesoporous Materials 225 (2016) 385–391. https://doi.org/10.1016/j.micromeso.2016.01.021.
  14. [14] L.E. Burris, M.C.G. Juenger, Effect of calcination on the reactivity of natural clinoptilolite zeolites used as supplementary cementitious materials, Constr Build Mater 258 (2020) 119988. https://doi.org/10.1016/j.conbuildmat.2020.119988.
  15. [15] C. Nico, T. Monteiro, M.P.F. Graça, Niobium oxides and niobates physical properties: Review and prospects, Prog Mater Sci 80 (2016) 1–37. https://doi.org/10.1016/j.pmatsci.2016.02.001.
  16. [16] T. Taher, A. Yoshida, A. Lesbani, I. Kurnia, G. Guan, A. Abudula, W. Ueda, Adsorptive removal and photocatalytic decomposition of cationic dyes on niobium oxide with deformed orthorhombic structure, J Hazard Mater 415 (2021) 125635. https://doi.org/10.1016/j.jhazmat.2021.125635.