Congo red dye adsorption using ZnAl layered double hydroxide fabricated using hydrothermal methods

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Published: Dec 28, 2024
DOI: https://doi.org/10.62755/greensusmater.2024.1.2.44-50
Keywords:
ZnAl LDH, hexamethylenetetramine, adsorption kinetics, isotherm, hydrothermal

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Anisa Fitri
Department of Materials Engineering, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
Febriwan Rizki Lumbanraja
Department of Materials Engineering, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
Istiara Rizqillah Hanifah
Department of Materials Engineering, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
Bayu Prasetya
Department of Materials Engineering, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia
Rizky Aflaha
Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara PO Box BLS 21, Yogyakarta, 55281, Indonesia
Septia Eka Marsha Putra
Department of Engineering Physics, Institut Teknologi Sumatera, Terusan Ryacudu, Way Hui, Jati Agung, Lampung Selatan 35365, Indonesia

Abstract

Industrial dye pollutants, particularly azo dyes like Congo red, pose significant environmental and health risks due to their toxic and non-biodegradable nature. This study assesses ZnAl Layered Double Hydroxide (ZnAl LDH) as an effective adsorbent, incorporating comprehensive materials characterization and adsorption isotherm analyses. Materials characterization using SEM and XRD confirmed the structural integrity and morphological suitability of ZnAl LDH for dye adsorption. Results demonstrated that ZnAl LDH, particularly the HMTA-based variant (h-ZnAl LDH), achieved superior adsorption capacities of up to 17.8 mg/g, significantly outperforming the urea-based (u-ZnAl LDH) with capacity of 12.3 mg/g. Kinetic analysis showed that the pseudo-second-order (PSO) model provided a better fit (R2 = 0.995) than the pseudo-first-order (PFO) model, indicating that chemisorption plays a dominant role in the adsorption mechanism. The adsorption process was also best described by the Langmuir isotherm model (R2 = 0.989), indicating monolayer adsorption on a homogeneous surface, while the Freundlich model (R2 = 0.944) also provided a reasonable fit, suggesting some degree of multilayer adsorption on heterogeneous surfaces. The superior performance of HMTA-based ZnAl LDH presents a significant advancement in wastewater treatment technologies

Article Details

How to Cite
Fitri, A., Lumbanraja, F. R., Hanifah, I. R., Prasetya, B., Aflaha, R., & Putra, S. E. M. (2024). Congo red dye adsorption using ZnAl layered double hydroxide fabricated using hydrothermal methods . Greensusmater, 1(2), 44–50. https://doi.org/10.62755/greensusmater.2024.1.2.44-50
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Vol. 1 No. 2 (2024): December
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